Pesticides in Sediments From Queensland Irrigation Channels and Drains     

Jochen F. Müller  Sabine Duquesne  Jack Ng  Glen R. Shaw  K Krrishnamohan  K Manonmanii  Mary Hodge  Geoff K. Eaglesham 《Marine pollution bulletin》2000,41(7-12):294-301

Pesticide concentration in sediment from irrigation areas can provide information required to assess exposure and fate of these chemicals in freshwater ecosystems and their likely impacts to the marine environment. In this study, 103 sediment samples collected from irrigation channels and drains in 11 agricultural areas of Queensland were analysed for a series of past and presently used pesticides including various organochlorines, synthetic pyrethroids, benzoyl ureas, triazines and organophosphates. The most often detected compounds were endosulphans (, β and/or endosulphan sulphate) which were detectable in 78 of the 103 samples and levels ranged from below the limit of quantification (0.1 ng g⁻¹ dw) up to 840 ng g⁻¹ dw. DDT and its metabolites were the second most often detected pesticide investigated (74 of the 103 samples) with concentrations up to 240 ng g⁻¹ dw of ∑DDTs. Mean ∑endosulphan and ∑DDT concentrations were 1–2 orders of magnitude higher in sediments from the irrigation areas which are dominated by cotton cultivation compared to those which are dominated by sugarcane cultivation. In contrast to these insecticides, the herbicides diuron, atrazine and ametryn were the compounds which were most often detected in sediments from irrigation drains in sugarcane areas with maximum concentrations in areas of 120, 70 and 130 ng g⁻¹ dw, respectively. In particular during flood events, when light is limiting, transport of these photosynthesis inhibiting herbicides from the sugarcane cultivation areas to the marine environment may result in additional stress of marine plants.  相似文献   

Semiparametric regression models for spatial prediction and uncertainty quantification of soil attributes     

Hunter?R.?Merrill  Sabine?Grunwald  Nikolay?BliznyukEmail authorView author&#;s OrcID profile 《Stochastic Environmental Research and Risk Assessment (SERRA)》2017,31(10):2691-2703

In many studies, the distribution of soil attributes depends on both spatial location and environmental factors, and prediction and process identification are performed using existing methods such as kriging. However, it is often too restrictive to model soil attributes as dependent on a known, parametric function of environmental factors, which kriging typically assumes. This paper investigates a semiparametric approach for identifying and modeling the nonlinear relationships of spatially dependent soil constituent levels with environmental variables and obtaining point and interval predictions over a spatial region. Frequentist and Bayesian versions of the proposed method are applied to measured soil nitrogen levels throughout Florida, USA and are compared to competing models, including frequentist and Bayesian kriging, based an array of point and interval measures of out-of-sample forecast quality. The semiparametric models outperformed competing models in all cases. Bayesian semiparametric models yielded the best predictive results and provided empirical coverage probability nearly equal to nominal.  相似文献   

A Critical Analysis of Transverse Dispersivity Field Data     

Alraune Zech  Sabine Attinger  Alberto Bellin  Vladimir Cvetkovic  Peter Dietrich  Aldo Fiori  Georg Teutsch  Gedeon Dagan 《Ground water》2019,57(4):632-639

Transverse dispersion, or tracer spreading orthogonal to the mean flow direction, which is relevant e.g, for quantifying bio-degradation of contaminant plumes or mixing of reactive solutes, has been studied in the literature less than the longitudinal one. Inferring transverse dispersion coefficients from field experiments is a difficult and error-prone task, requiring a spatial resolution of solute plumes which is not easily achievable in applications. In absence of field data, it is a questionable common practice to set transverse dispersivities as a fraction of the longitudinal one, with the ratio 1/10 being the most prevalent. We collected estimates of field-scale transverse dispersivities from existing publications and explored possible scale relationships as guidance criteria for applications. Our investigation showed that a large number of estimates available in the literature are of low reliability and should be discarded from further analysis. The remaining reliable estimates are formation-specific, span three orders of magnitude and do not show any clear scale-dependence on the plume traveled distance. The ratios with the longitudinal dispersivity are also site specific and vary widely. The reliability of transverse dispersivities depends significantly on the type of field experiment and method of data analysis. In applications where transverse dispersion plays a significant role, inference of transverse dispersivities should be part of site characterization with the transverse dispersivity estimated as an independent parameter rather than related heuristically to longitudinal dispersivity.  相似文献   

Strategies to improve the explanatory power of a dynamic slope stability model by enhancing land cover parameterisation and model complexity     

Elmar M. Schmaltz  L.P.H. Van Beek  Thom A. Bogaard  Sabine Kraushaar  Stefan Steger  Thomas Glade 《地球表面变化过程与地形》2019,44(6):1259-1273

Despite the importance of land cover on landscape hydrology and slope stability, the representation of land cover dynamics in physically based models and their associated ecohydrological effects on slope stability is rather scarce. In this study, we assess the impact of different levels of complexity in land cover parameterisation on the explanatory power of a dynamic and process-based spatial slope stability model. Firstly, we present available and collected data sets and account for the stepwise parameterisation of the model. Secondly, we present approaches to simulate land cover: 1) a grassland landscape without forest coverage; 2) spatially static forest conditions, in which we assume limited knowledge about forest composition; 3) more detailed information of forested areas based on the computation of leaf area development and the implementation of vegetation-related processes; 4) similar to the third approach but with the additional consideration of the spatial expansion and vertical growth of vegetation. Lastly, the model is calibrated based on meteorological data sets and groundwater measurements. The model results are quantitatively validated for two landslide-triggering events that occurred in Western Austria. Predictive performances are estimated using the Area Under the receiver operating characteristic Curve (AUC). Our findings indicate that the performance of the slope stability model was strongly determined by model complexity and land cover parameterisation. The implementation of leaf area development and land cover dynamics further yield an acceptable predictive performance (AUC ~0.71-0.75) and a better conservativeness of the predicted unstable areas (FoC ~0.71). The consideration of dynamic land cover expansion provided better performances than the solely consideration of leaf area development. The results of this study highlight that an increase of effort in the land cover parameterisation of a dynamic slope stability model can increase the explanatory power of the model. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

The vulnerability of beach tourism to climate change—an index approach   总被引：2，自引：0，他引：2  

Sabine L. Perch-Nielsen 《Climatic change》2010,100(3-4):579-606

The attractiveness of a region for touristic activities depends strongly on the local weather and climate. This paper analyses the vulnerability of the beach tourism sector towards climate change by means of an index approach on a country level. A vulnerability framework for the tourism sector is developed and on its basis, indicators are defined for exposure, sensitivity and adaptive capacity. A transparent index approach, including a robustness analysis with multiple transformation methods and weighting sets, yields an assessment of the overall relative vulnerability of the beach tourism sector in 51 countries. Aggregate results on an annual level are presented as a starting point for a more detailed comparison of countries based on the individual indicators. The important limitations regarding the availability of accurate indicators as well as the concept of vulnerability itself are discussed. Despite these limitations, the present study contributes to integrating the numerous direct as well as indirect effects climate change may have on beach tourism.  相似文献   

Westerlund 1: bound or unbound?     

Sabine Mengel  Lowell E. Tacconi-Garman 《Astrophysics and Space Science》2009,324(2-4):321-325

The Galactic open cluster Westerlund 1 (Wd 1) represents the ideal local template for extragalactic young massive star clusters, because it is currently the only nearby young cluster with a mass of ～10⁵?M_⊙. Its proximity makes spatially resolved studies of its stellar population feasible, and additionally permits direct comparison of its properties with measurements of velocity dispersion and dynamical mass for spatially unresolved extragalactic clusters. Recently, we published the dynamical mass estimate based on spectra of four red supergiants. We have now identified six additional stars which allow a determination of radial velocity from the wavelength covered in our VLT/ISAAC near-infrared spectra (CO bandhead region near 2.29 μm), significantly improving statistics. Using a combination of stepping and scanning the slit across the cluster center, we covered an area which included the following suitable spectral types: four red supergiants, five yellow hypergiants, and one B-type emission-line star. Our measured velocity dispersion is 9.2 km?s^?1. Together with the cluster size of 0.86 pc, derived from archival near-infrared SOFI-NTT images, this yields a dynamical mass of 1.5×10⁵ M_⊙. Comparing this to the mass derived via photometry, there is no indication that the cluster is currently undergoing dissolution.  相似文献   

Impact of fertilizer application and urban wastes on the quality of groundwater in the Cambrai Chalk aquifer,Northern France     

Hani Serhal  Daniel Bernard  Jamal El Khattabi  Bastin-Lacherez Sabine  Isam Shahrour 《Environmental Geology》2009,57(7):1579-1592

Since 1975, Europe sets up its policy to limit the degradation and the pollution of the aquatic environments through 30 directives and regulations. In the north of France, the nitrate concentrations measured in the groundwater exceed the water drinking limit fixed at 50 mg/L by the European framework directive in the field of water (2000/60/EC). This high concentration is due to intensive agriculture, industrialization and demographic growth. Several programs were launched in order to resolve this situation: “Ferti-better” or the use of fertilizer in moderation and installation and amelioration of wastewater collect and treatment systems. In order to estimate the influence of the anthropic activities on the quality of groundwater in the “Artois-Picardy” basin, a preliminary validation on parcel and district scale were necessary. The impact of these programs in the “Cambrai district” was evaluated using an integrated approach, which is based on the use of four numerical models: AgriFlux, VS2DT, Modflow and MT3D. The results illustrate an improvement due to the “Ferti-Better” program initiated in 1990 and punctual degradation under urbanized areas. Predictions (2015) show a spatial evolution of nitrates concentration varying with the thickness of unsaturated layer. The integrated model constitutes an efficient tool for predicting the evolution of the groundwater quality. This approach is important to control the application of the new European laws in the water field.  相似文献   

Biogeochemical controls on authigenic carbonate formation at the Chapopote “asphalt volcano”, Bay of Campeche   总被引：1，自引：0，他引：1  

Thomas H. Naehr  Daniel Birgel  Gerhard Bohrmann  Ian R. MacDonald  Sabine Kasten   《Chemical Geology》2009,266(3-4):399-411

The Campeche Knolls in the Bay of Campeche, southern Gulf of Mexico, were investigated through detailed seafloor mapping, ROV surveys, and sediment and pore water sampling. The knolls are elongated, submarine hills created by salt tectonics with a positive relief of up to 800 m above the surrounding seafloor. Several of the knolls are associated with sea-surface oil slicks identified from satellite data, indicating the presence of hydrocarbon seeps on the seafloor. One of the knolls, named “Chapopote”, was studied in detail during two international research expeditions (SO174/2 and M67/2) and is characterized by extensive hydrocarbon seepage including large asphalt flows, oil and gas seeps, and seafloor gas hydrate deposits. Chemosymbiotic biological communities and authigenic carbonate deposits are associated with the seeps and are the result of both biogeochemical turnover and the interaction between downward-diffusing seawater and hydrocarbon-rich pore fluids at shallow sediment depth. Authigenic carbonates are characterized by aragonite, exhibit a porous texture, and are cemented by a matrix of microsparitic to sparitic aragonite. Macropores of the carbonates were completely filled with liquid oil. Carbonate microfabrics include peloidal or clotted fabrics that may indicate the existence of microenvironments resulting from microbial metabolism. Banded/botryoidal aragonite cements line the intra- and bioclasts and incompletely fill the pore spaces. The stable carbon isotopic composition of authigenic aragonite varies between − 28.6‰ and − 17.9‰ (PDB), identifying oil oxidation as the primary source of carbon to the DIC pool, while lipid biomarker data demonstrate the concurrent existence of microbial communities responsible for anaerobic oxidation of methane (AOM). These observations indicate the presence of additional, AOM-independent reactions responsible for carbon sequestration at hydrocarbon seeps and demonstrate the complexity of biogeochemical processes at seep sites in the Gulf of Mexico basin. Oxygen isotope data of authigenic aragonite vary from + 2.5‰ to + 3.8‰ (PDB), indicating carbonate precipitation in slight disequilibrium with the surrounding pore fluids.  相似文献   

The ‘Roxolany Tephra’ (Ukraine) − new evidence for an origin from Ciomadul volcano,East Carpathians          下载免费PDF全文

Sabine Wulf  Stanisław Fedorowicz  Daniel Veres  Maria Łanczont  Dávid Karátson  Ralf Gertisser  Marc Bormann  Enikö Magyari  Oona Appelt  Ulrich Hambach  Petro F. Gozhyk 《第四纪科学杂志》2016,31(6):565-576

  相似文献   

Grain coarsening in polymineralic contact metamorphic carbonate rocks: The role of different physical interactions during coarsening     

Sabine H. Brodhag  Marco Herwegh  Alfons Berger 《Journal of Structural Geology》2011,33(4):698-712

The microstructural evolution of polymineralic contact metamorphic calcite marbles (Adamello contact aureole) with variable volume fractions of second-phase minerals were quantitatively analyzed in terms of changes in grain size and nearest neighbor relations, as well as the volume fractions, dispersion and occurrences of the second phases as a function of changing metamorphic conditions. In all samples, the calcite grain size is controlled by pinning of grain boundaries by second phases, which can be expressed by the Zener parameter (Z), i.e., the ratio between size and volume fraction of the second phases. With increasing peak metamorphic temperature, both the sizes of matrix grains and second phases increase in dependence on the second-phase volume fraction. Two distinct coarsening trends are revealed: trend I with coupled grain coarsening limited by the growth of the second phases is either characterized by large-sized or a large number of closely spaced-second phase particles, and results finally in a dramatic increase in the calcite grain size with Z. Trend II is manifest by matrix controlled grain growth, which is retarded by the presence of single second-phase particles that are located on calcite grain boundaries. It is supported by grain boundary pinning induced by triple junctions, and the calcite grain size increases moderately with Z. The two different grain coarsening trends manifest the transition between relatively pure polymineralic aggregates (trend II) and microstructures with considerable second-phase volume fractions of up to 0.5. The variations might be of general validity for any polymineralic rock, which undergoes grain coarsening during metamorphism. The new findings are important for a better understanding of the initiation of strain localization based on the activation of grain size dependent deformation mechanisms.  相似文献